Head to Head
| Qatar Open Women | 2017/09/14 11:30 | Karoline Mischek v Maria Xiao | L | 1-3 |
Home History
| Bulgaria Open Women | 2019/08/13 07:30 | Ivet Ilieva v Karoline Mischek | W | 2-4 |
| Croatia Open U21 Women | 2019/05/15 12:10 | Karoline Mischek v Aleksandra Vovk | L | 1-3 |
| Slovenia Open U21 Women | 2019/05/09 18:00 | Karoline Mischek v Sreeja Akula | L | 0-3 |
| Slovenia Open Women | 2019/05/09 09:00 | Karoline Mischek v Hsin Huang | L | 2-3 |
| World Championship Women | 2019/04/23 10:30 | Sarah De Nutte v Karoline Mischek | L | 4-2 |
| Czech Extraleague | 2019/03/23 12:30 | Karoline Mischek v Barbora Balazova | L | 2-4 |
| Qatar Open XD | 2019/03/22 08:30 | Ana Garcia v Karoline Mischek | L | 3-2 |
| Czech Extraleague | 2019/03/20 06:40 | Karoline Mischek v Olga Vishnyakova | W | 3-1 |
Away History
| Bulgaria Open Women | 2019/08/13 07:30 | Zi Mu v Maria Xiao | L | 4-2 |
| Australian Open Women | 2019/07/10 03:50 | Maria Xiao v Weishan Liu | L | 2-4 |
| Australian Open Women | 2019/07/09 05:50 | Maria Xiao v Melissa Tapper | W | 4-0 |
| European Games Women | 2019/06/22 13:00 | Maria Xiao v Viktoria Pavlovich | L | 2-4 |
| Hong Kong Open Women | 2019/06/05 02:40 | Mingyang Sun v Maria Xiao | L | 4-1 |
| World Championship Women | 2019/04/23 08:00 | Nam Hae Kim v Maria Xiao | L | 4-2 |
| Czech Extraleague | 2019/03/22 16:55 | Yu-Jhun Li v Maria Xiao | L | 4-1 |
| Czech Extraleague | 2019/03/22 09:50 | Jennifer Jonsson v Maria Xiao | W | 0-4 |