[3] Borussia Dortmund 0-0 Barcelona [3] 2019-09-17 19:00
Stadium: Signal Iduna Park Round: 1
Referee: Ovidiu Alin Hategan Home Manager: Lucien Favre Away Manager: Ernesto Valverde
Home History
| Germany Bundesliga I | 2019/09/14 13:30 | Borussia Dortmund v Bayer Leverkusen | W | 4-0 |
| Elite Club Friendlies | 2019/09/06 15:00 | Cottbus v Borussia Dortmund | W | 0-5 |
| Germany Bundesliga I | 2019/08/31 16:30 | Union Berlin v Borussia Dortmund | L | 3-1 |
| Germany Bundesliga I | 2019/08/23 18:30 | Cologne v Borussia Dortmund | W | 1-3 |
| Germany Bundesliga I | 2019/08/17 13:30 | Borussia Dortmund v Augsburg | W | 5-1 |
| Elite Club Friendlies | 2019/08/10 13:01 | SC Preussen Munster v Borussia Dortmund | W | 0-4 |
| Germany DFB Pokal | 2019/08/09 18:45 | KFC Uerdingen 05 v Borussia Dortmund | W | 0-2 |
| Germany Super Cup | 2019/08/03 18:30 | Borussia Dortmund v Bayern Munich | W | 2-0 |
Away History
| Spain La Liga | 2019/09/14 19:00 | Barcelona v Valencia | W | 5-2 |
| Spain La Liga | 2019/08/31 15:00 | Osasuna v Barcelona | D | 2-2 |
| Spain La Liga | 2019/08/25 19:00 | Barcelona v Real Betis | W | 5-2 |
| Spain La Liga | 2019/08/16 19:00 | Athletic Bilbao v Barcelona | L | 1-0 |
| Elite Club Friendlies | 2019/08/10 21:00 | Napoli v Barcelona | W | 0-4 |
| Elite Club Friendlies | 2019/08/07 23:30 | Barcelona v Napoli | W | 2-1 |
| Elite Club Friendlies | 2019/08/04 18:00 | Barcelona v Arsenal | W | 2-1 |
| Elite Club Friendlies | 2019/07/27 09:00 | Vissel Kobe v Barcelona | W | 0-2 |