Stadium: PEDRO AMADEU Round: 25 Ground: Clay
| ITF Germany F8 | 2016/07/20 09:00 | Daniel Masur v Caio Zampieri | 5-7,6-4,7-5 |
| ITF France F12 | 2016/07/02 12:00 | Caio Zampieri v Constant Lestienne | 3-6,4-6 |
| ITF France F12 | 2016/07/01 08:30 | Caio Zampieri v Florent Diep | 7-6,6-1 |
| ITF France F12 | 2016/06/29 10:00 | Caio Zampieri v Matteo Viola | 6-2,6-4 |
| ITF France F12 | 2016/06/27 10:15 | Caio Zampieri v Juan Ignacio Iliev | 6-1,6-1 |
| ITF Netherlands F2 | 2016/06/22 08:50 | Caio Zampieri v Yann Marti | 1-6,1-6 |
| Challenger Caltanissetta Qual | 2016/06/04 12:00 | Caio Zampieri v Andres Molteni | 6-3,3-6,4-6 |
| Challenger Vicenza Qual | 2016/05/21 08:00 | Tim Van Rijthoven v Caio Zampieri | 7-5,6-3 |
| Challenger Curitiba Qual | 2016/08/28 15:00 | Alex Blumenberg v Caio Silva | 6-4,4-6,2-6 |
| ITF Georgia F2 | 2016/08/04 06:00 | Lukas Mugevicius v Caio Silva | 6-1,6-3 |
| ITF Georgia F2 | 2016/08/02 07:30 | Michael Avetisyan v Caio Silva | 0-6,0-6 |
| ITF Georgia F1 | 2016/07/27 09:10 | George Tsivadze v Caio Silva | 4-6,6-1,6-4 |
| ITF Belgium F5 | 2016/07/12 14:35 | Caio Silva v Laurens Verboven | 4-6,2-6 |
| ITF Austria F1 | 2016/07/05 15:25 | Caio Silva v Goncalo Oliveira | 6-7,2-6 |
| ITF Belgium F3 | 2016/06/28 09:15 | Jakob Johansson-Holm v Caio Silva | 6-3,7-6 |
| ITF Spain F17 | 2016/06/16 14:00 | Caio Silva v Remi Boutillier | 0-6,2-6 |