[39] Sloane Stephens 6-2,2-6,2-6 Serena Williams [8] 2020-09-05 18:10
Stadium: Arthur Ashe Stadium Round: 25 Ground: Hardcourt outdoor
Home History
| US Open Women | 2020/09/03 20:50 | Sloane Stephens v Olga Govortsova | 6-2,6-2 |
| US Open Women | 2020/09/02 00:15 | Sloane Stephens v Mihaela Buzarnescu | 6-3,6-3 |
| WTA New York | 2020/08/23 20:10 | Sloane Stephens v Caroline Garcia | 3-6,6-7 |
| WTA Lexington | 2020/08/11 21:20 | Leylah Annie Fernandez v Sloane Stephens | 6-3,6-3 |
| US Invitational Women | 2020/06/28 00:10 | Jennifer Brady v Sloane Stephens | 6-2,7-6 |
| US Invitational Women | 2020/06/27 01:45 | Eugenie Bouchard v Sloane Stephens | 3-6,6-7 |
| WTA Monterrey | 2020/03/05 01:50 | Leylah Annie Fernandez v Sloane Stephens | 6-7,6-3,6-3 |
| WTA Monterrey | 2020/03/03 03:45 | Emma Navarro v Sloane Stephens | 4-6,7-5,1-6 |
Away History
| US Open Women | 2020/09/03 23:00 | Margarita Betova v Serena Williams | 2-6,4-6 |
| US Open Women | 2020/09/01 21:05 | Kristie Ahn v Serena Williams | 5-7,3-6 |
| WTA New York | 2020/08/26 00:40 | Maria Sakkari v Serena Williams | 5-7,7-6,6-1 |
| WTA New York | 2020/08/24 17:00 | Arantxa Rus v Serena Williams | 6-7,6-3,6-7 |
| WTA Lexington | 2020/08/14 19:15 | Serena Williams v Shelby Rogers | 6-1,4-6,6-7 |
| WTA Lexington | 2020/08/13 16:45 | Serena Williams v Venus Williams | 3-6,6-3,6-4 |
| WTA Lexington | 2020/08/11 15:00 | Serena Williams v Bernarda Pera | 4-6,6-4,6-1 |
| 2020 Fed Cup | 2020/02/09 01:45 | Serena Williams v Anastasija Sevastova | 6-7,6-3,6-7 |