[18] Barcelona 4-0 Villarreal [6] 2020-09-27 19:00
Stadium: Camp Nou Round: 3
Referee: Guillermo Cuadra Fernandez Home Manager: Ronald Koeman Away Manager: Unai Emery
Head to Head
| Spain La Liga | 2020/07/05 20:00 | Villarreal v Barcelona | W | 1-4 |
| Spain La Liga | 2019/09/24 19:00 | Barcelona v Villarreal | W | 2-1 |
| Spain La Liga | 2019/04/02 19:30 | Villarreal v Barcelona | D | 4-4 |
| Spain La Liga | 2018/12/02 17:30 | Barcelona v Villarreal | W | 2-0 |
| Spain La Liga | 2018/05/09 18:00 | Barcelona v Villarreal | W | 5-1 |
| Spain La Liga | 2017/12/10 19:45 | Villarreal v Barcelona | W | 0-2 |
| Spain La Liga | 2017/05/06 16:30 | Barcelona v Villarreal | W | 4-1 |
| Spain La Liga | 2017/01/08 19:45 | Villarreal v Barcelona | D | 1-1 |
Home History
| Elite Club Friendlies | 2020/09/19 17:00 | Barcelona v Elche | W | 1-0 |
| Europe Friendlies | 2020/09/16 17:00 | Barcelona v Girona | W | 3-1 |
| Elite Club Friendlies | 2020/09/12 17:00 | Barcelona v Gimnastic | W | 3-1 |
| UEFA Champions League | 2020/08/14 19:00 | Barcelona v Bayern Munich | L | 2-8 |
| UEFA Champions League | 2020/08/08 19:00 | Barcelona v Napoli | W | 3-1 |
| Spain La Liga | 2020/07/19 15:00 | CD Alaves v Barcelona | W | 0-5 |
| Spain La Liga | 2020/07/16 19:00 | Barcelona v Osasuna | L | 1-2 |
| Spain La Liga | 2020/07/11 17:30 | Valladolid v Barcelona | W | 0-1 |
Away History
| Spain La Liga | 2020/09/19 14:00 | Villarreal v Eibar | W | 2-1 |
| Spain La Liga | 2020/09/13 16:30 | Villarreal v Huesca | D | 1-1 |
| Elite Club Friendlies | 2020/09/05 18:30 | Villarreal v Levante | L | 1-2 |
| Elite Club Friendlies | 2020/09/02 17:00 | Villarreal v Real Sociedad | W | 2-0 |
| Elite Club Friendlies | 2020/08/28 18:00 | Villarreal v Valencia | L | 1-2 |
| Europe Friendlies | 2020/08/25 18:00 | Villarreal v Tenerife | L | 2-3 |
| Europe Friendlies | 2020/08/23 17:00 | Villarreal v FC Cartagena | W | 3-1 |
| Spain La Liga | 2020/07/19 16:30 | Villarreal v Eibar | W | 4-0 |