[7] Villarreal 1-2 Barcelona [3] 2021-04-25 14:15
Stadium: Estadio de la Ceramica Round: 32
Referee: Carlos Del Cerro Grande Home Manager: Unai Emery Away Manager: Ronald Koeman
Head to Head
| Spain La Liga | 2020/09/27 19:00 | Barcelona v Villarreal | L | 4-0 |
| Spain La Liga | 2020/07/05 20:00 | Villarreal v Barcelona | L | 1-4 |
| Spain La Liga | 2019/09/24 19:00 | Barcelona v Villarreal | L | 2-1 |
| Spain La Liga | 2019/04/02 19:30 | Villarreal v Barcelona | D | 4-4 |
| Spain La Liga | 2018/12/02 17:30 | Barcelona v Villarreal | L | 2-0 |
| Spain La Liga | 2018/05/09 18:00 | Barcelona v Villarreal | L | 5-1 |
| Spain La Liga | 2017/12/10 19:45 | Villarreal v Barcelona | L | 0-2 |
| Spain La Liga | 2017/05/06 16:30 | Barcelona v Villarreal | L | 4-1 |
Home History
| Spain La Liga | 2021/04/21 19:00 | CD Alaves v Villarreal | L | 2-1 |
| Spain La Liga | 2021/04/18 19:00 | Levante v Villarreal | W | 1-5 |
| UEFA Europa League | 2021/04/15 19:00 | Villarreal v Dinamo Zagreb | W | 2-1 |
| Spain La Liga | 2021/04/11 12:00 | Villarreal v Osasuna | L | 1-2 |
| UEFA Europa League | 2021/04/08 19:00 | Dinamo Zagreb v Villarreal | W | 0-1 |
| Spain La Liga | 2021/04/03 12:00 | Granada v Villarreal | W | 0-3 |
| Spain La Liga | 2021/03/21 15:15 | Villarreal v Cadiz | W | 2-1 |
| UEFA Europa League | 2021/03/18 20:00 | Villarreal v Dynamo Kiev | W | 2-0 |
Away History
| Spain La Liga | 2021/04/22 20:00 | Barcelona v Getafe | W | 5-2 |
| Spain Copa del Rey | 2021/04/17 19:30 | Athletic Bilbao v Barcelona | W | 0-4 |
| Spain La Liga | 2021/04/10 19:00 | Real Madrid v Barcelona | L | 2-1 |
| Spain La Liga | 2021/04/05 19:00 | Barcelona v Valladolid | W | 1-0 |
| Spain La Liga | 2021/03/21 20:00 | Real Sociedad v Barcelona | W | 1-6 |
| Spain La Liga | 2021/03/15 20:00 | Barcelona v Huesca | W | 4-1 |
| UEFA Champions League | 2021/03/10 20:00 | PSG v Barcelona | D | 1-1 |
| Spain La Liga | 2021/03/06 20:00 | Osasuna v Barcelona | W | 0-2 |