Stadium: Court 10 Round: 25 Ground: Clay
| ITF W60 Bellinzona | 2021/04/07 09:00 | Martina Di Giuseppe v Ekaterine Gorgodze | 1-6,4-6 |
| ITF W25 Grenoble | 2021/02/09 08:50 | Cristina Bucsa v Martina Di Giuseppe | 6-4,6-4 |
| ITF W60 Andrezieux-Boutheon | 2021/01/27 12:35 | Martina Di Giuseppe v Rebecca Sramkova | 4-6,4-6 |
| Australian Open Women | 2021/01/11 07:10 | Margarita Betova v Martina Di Giuseppe | 6-3,4-6,6-2 |
| French Open Women | 2020/09/24 10:30 | Dalma Galfi v Martina Di Giuseppe | 6-2,6-3 |
| French Open Women | 2020/09/22 12:35 | Martina Di Giuseppe v Usue Maitane Arconada | 6-2,6-4 |
| WTA Rome | 2020/09/12 08:00 | Martina Di Giuseppe v Anna-Lena Friedsam | 3-6,2-6 |
| WTA Prague | 2020/09/01 08:00 | Robin Anderson v Martina Di Giuseppe | 6-4,6-3 |
| ITF W60 Oeiras | 2021/04/13 15:30 | Sina Herrmann v Despina Papamichail | 2-6,6-1,6-7 |
| ITF W25 Cordoba | 2021/04/08 13:00 | Despina Papamichail v Panna Udvardy | 3-6,6-2,2-6 |
| ITF W25 Cordoba | 2021/04/07 15:10 | Andrea Lazaro Garcia v Despina Papamichail | 4-6,5-7 |
| ITF W25 Villa Maria | 2021/04/01 17:35 | Susan Bandecchi v Despina Papamichail | 6-0,7-6 |
| ITF W25 Villa Maria | 2021/03/30 17:55 | Despina Papamichail v Diana Marcinkevica | 1-6,7-6,6-3 |
| ITF W25 Buenos Aires | 2021/03/23 15:55 | Despina Papamichail v Yuki Naito | 6-1,1-6,4-6 |
| ITF W25 Newport Beach | 2021/03/05 17:30 | Beatriz Haddad Maia v Despina Papamichail | 6-0,7-5 |
| ITF W25 Newport Beach | 2021/03/03 22:00 | Katherine Sebov v Despina Papamichail | 4-6,7-6,3-6 |