Stadium: Court 3 Round: 25 Ground: Clay
| WTA Madrid WD | 2021/05/05 10:30 | Xu/Zhang v Krejcikova/Siniakova | 1-6,0-6 |
| WTA Madrid WD | 2021/05/03 09:00 | Xu/Zhang v Fichman/Olmos | 6-4,6-3 |
| WTA Madrid WD | 2021/04/29 10:40 | Xu/Zhang v Gauff/Melichar | 7-5,7-5 |
| WTA Stuttgart WD | 2021/04/22 13:30 | Barty/Brady v Xu/Zhang | 6-4,6-3 |
| WTA Stuttgart WD | 2021/04/21 15:35 | Middendorf/Akugue v Xu/Zhang | 6-7,4-6 |
| Billie Jean King Cup | 2021/04/17 15:40 | Rus/Schuurs v Xu/Zhang | 6-1,6-4 |
| WTA Charleston WD | 2021/04/07 20:15 | Xu/Zhang v Dolehide/Navarro | 1-6,4-6 |
| WTA Miami WD | 2021/03/28 17:25 | Mattek-Sands/Swiatek v Xu/Zhang | 6-3,6-1 |
| WTA Madrid WD | 2021/05/06 11:00 | Dabrowski/Schuurs v Perez/Zheng | 6-2,6-4 |
| WTA Madrid WD | 2021/05/04 09:00 | Perez/Zheng v Guarachi/Krawczyk | 6-4,6-4 |
| WTA Madrid WD | 2021/04/29 13:45 | Perez/Zheng v Christian/Santamaria | 6-2,2-6,10-7 |
| WTA Miami WD | 2021/03/26 23:25 | Babos/Kudermetova v Perez/Zheng | 3-6,6-4,10-7 |