Stadium: Centre Court Round: 25 Ground: Clay
| WTA Lexington | 2020/08/10 14:00 | Francesca Di Lorenzo v Olga Govortsova | 1-6,2-6 |
| ITF W60 Montpellier | 2021/06/30 15:10 | Francesca Di Lorenzo v Tessah Andrianjafitrimo | 1-6,4-6 |
| Wimbledon Women | 2021/06/22 17:25 | Isabella Shinikova v Francesca Di Lorenzo | 2-6,7-6,6-2 |
| ITF W100 Nottingham | 2021/06/13 09:00 | Francesca Di Lorenzo v Jana Fett | 5-7,2-6 |
| French Open Women | 2021/05/26 16:20 | Elisabetta Cocciaretto v Francesca Di Lorenzo | 7-6,6-0 |
| French Open Women | 2021/05/25 13:15 | Priscilla Hon v Francesca Di Lorenzo | 5-7,3-6 |
| ITF W100 Bonita Springs | 2021/05/14 21:00 | Francesca Di Lorenzo v Hanna Chang | 3-6,3-6 |
| ITF W100 Bonita Springs | 2021/05/14 14:50 | Mayar Sherif v Francesca Di Lorenzo | 4-6,6-1,4-6 |
| ITF W100 Bonita Springs | 2021/05/12 15:35 | Francesca Di Lorenzo v Caroline Dolehide | 6-2,6-7,7-6 |
| Wimbledon Women | 2021/06/30 14:00 | Olga Govortsova v Coco Vandeweghe | 4-6,2-6 |
| Wimbledon Women | 2021/06/25 10:30 | Cristina Bucsa v Olga Govortsova | 3-6,2-6 |
| Wimbledon Women | 2021/06/24 10:00 | Rebecca Sramkova v Olga Govortsova | 6-4,6-7,2-6 |
| Wimbledon Women | 2021/06/23 11:30 | Marie Benoit v Olga Govortsova | 5-7,4-6 |
| WTA Bol | 2021/06/09 08:30 | Jasmine Paolini v Olga Govortsova | 6-1,4-6,6-3 |
| WTA Bol | 2021/06/08 10:35 | Lulu Sun v Olga Govortsova | 3-6,6-7 |
| French Open Women | 2021/05/30 13:25 | Elena Vesnina v Olga Govortsova | 6-1,6-0 |
| French Open Women | 2021/05/27 13:30 | Aleksandra Krunic v Olga Govortsova | 6-2,6-3 |