Stadium: Court 1 Round: 53 Ground: Hardcourt outdoor
| Olympics 2020 - XD | 2021/07/30 11:00 | Vesnina/Karatsev v Stojanovic/Djokovic | 7-6,7-5 |
| Olympics 2020 - XD | 2021/07/29 11:50 | Siegemund/Krawietz v Stojanovic/Djokovic | 1-6,2-6 |
| Olympics 2020 - XD | 2021/07/28 10:30 | Stojanovic/Djokovic v Stefani/Melo | 6-3,6-4 |
| Olympics 2020 - XD | 2021/07/30 08:05 | Pavlyuchenkova/Rublev v Barty/Peers | 5-7,6-4,13-11 |
| Olympics 2020 - XD | 2021/07/29 09:50 | Barty/Peers v Sakkari/Tsitsipas | 6-4,4-6,10-6 |
| Olympics 2020 - XD | 2021/07/28 08:00 | Barty/Peers v Podoroska/Zeballos | 6-1,7-6 |