Head to Head
| Netherlands Eredivisie Women | 2021/05/30 12:30 | PSV Women v FC Twente Women | W | 2-1 |
| Netherlands Eredivisie Women | 2021/05/02 10:15 | FC Twente Women v PSV Women | L | 2-1 |
| Netherlands Eredivisie Women | 2021/03/30 17:30 | PSV Women v FC Twente Women | L | 1-2 |
| Netherlands Cup Women | 2021/02/28 13:30 | FC Twente Women v PSV Women | D | 1-1 |
| Netherlands Eredivisie Women | 2020/11/15 13:30 | FC Twente Women v PSV Women | L | 3-2 |
| Netherlands Eredivisie Women | 2019/12/01 13:30 | PSV Women v FC Twente Women | W | 1-0 |
| Netherlands Eredivisie Women | 2019/09/15 12:30 | FC Twente Women v PSV Women | W | 2-3 |
| Netherlands Eredivisie Women | 2019/04/26 17:30 | PSV Women v FC Twente Women | L | 2-3 |
Home History
| Netherlands Eredivisie Women | 2021/09/12 10:15 | Excelsior Barendrecht Women v PSV Women | D | 3-3 |
| Netherlands Eredivisie Women | 2021/08/27 17:30 | PSV Women v PEC Zwolle Women | W | 3-0 |
| UEFA Women's Champions League | 2021/08/21 16:00 | Arsenal Women v PSV Women | L | 3-1 |
| UEFA Women's Champions League | 2021/08/18 17:00 | Lokomotiv Moscow Women v PSV Women | W | 1-3 |
| Women’s Friendly | 2021/08/04 12:00 | Wolfsburg Women v PSV Women | L | 2-1 |
| Netherlands Cup Women | 2021/06/05 18:00 | ADO Den Haag Women v PSV Women | W | 0-1 |
| Netherlands Eredivisie Women | 2021/05/30 12:30 | PSV Women v FC Twente Women | W | 2-1 |
| Netherlands Eredivisie Women | 2021/05/23 12:30 | Ajax Women v PSV Women | L | 3-2 |
Away History
| Netherlands Eredivisie Women | 2021/09/12 14:45 | FC Twente Women v PEC Zwolle Women | L | 1-4 |
| UEFA Women's Champions League | 2021/09/09 18:00 | Benfica Women v FC Twente Women | L | 4-0 |
| Netherlands Eredivisie Women | 2021/09/05 10:15 | Ajax Women v FC Twente Women | W | 0-1 |
| UEFA Women's Champions League | 2021/08/31 17:30 | FC Twente Women v Benfica Women | D | 1-1 |
| Netherlands Eredivisie Women | 2021/08/27 17:30 | FC Twente Women v AZ Women | W | 8-0 |
| UEFA Women's Champions League | 2021/08/21 17:00 | FC Twente Women v ZFK Spartak Subotica Women | W | 5-3 |
| UEFA Women's Champions League | 2021/08/18 17:00 | FC Twente Women v KK Nike Women | W | 9-0 |
| Women’s Friendly | 2021/08/13 16:30 | Koln Women v FC Twente Women | D | 3-3 |