Head to Head
| UEFA Champions League Qualifying | 2021/08/18 19:00 | Benfica v PSV | L | 2-1 |
Home History
| Netherlands Eredivisie | 2021/08/21 18:00 | PSV v Cambuur Leeuwarden | W | 4-1 |
| UEFA Champions League Qualifying | 2021/08/18 19:00 | Benfica v PSV | L | 2-1 |
| Netherlands Eredivisie | 2021/08/14 16:45 | Heracles v PSV | W | 0-2 |
| UEFA Champions League Qualifying | 2021/08/10 18:00 | Midtjylland v PSV | W | 0-1 |
| Netherlands Super Cup | 2021/08/07 18:00 | Ajax v PSV | W | 0-4 |
| UEFA Champions League Qualifying | 2021/08/03 18:00 | PSV v Midtjylland | W | 3-0 |
| UEFA Champions League Qualifying | 2021/07/28 18:00 | Galatasaray v PSV | W | 1-2 |
| UEFA Champions League Qualifying | 2021/07/21 19:00 | PSV v Galatasaray | W | 5-1 |
Away History
| Portugal Primeira Liga | 2021/08/21 17:00 | Gil Vicente v Benfica | W | 0-2 |
| UEFA Champions League Qualifying | 2021/08/18 19:00 | Benfica v PSV | W | 2-1 |
| Portugal Primeira Liga | 2021/08/14 17:00 | Benfica v Arouca | W | 2-0 |
| UEFA Champions League Qualifying | 2021/08/10 19:00 | Benfica v Spartak Moscow | W | 2-0 |
| Portugal Primeira Liga | 2021/08/07 17:00 | Moreirense v Benfica | W | 1-2 |
| UEFA Champions League Qualifying | 2021/08/04 17:00 | Spartak Moscow v Benfica | W | 0-2 |
| Europe Friendlies | 2021/07/25 19:00 | Benfica v Marseille | D | 1-1 |
| Europe Friendlies | 2021/07/22 19:00 | Benfica v Lille | W | 1-0 |