Home History
| UEFA Women's Champions League | 2021/08/18 10:00 | Arsenal Women v Okzhetpes Women | W | 4-0 |
| Women’s Friendly | 2021/08/08 15:45 | Tottenham Women v Arsenal Women | W | 0-4 |
| Women’s Friendly | 2021/08/01 11:15 | Arsenal Women v Chelsea Women | W | 2-1 |
| England FA Cup Women | 2021/05/16 14:00 | Arsenal Women v Crystal Palace Women | W | 9-0 |
| England Super League Women | 2021/05/09 13:30 | Arsenal Women v Aston Villa Women | D | 0-0 |
| England Super League Women | 2021/05/02 12:00 | Everton Women v Arsenal Women | W | 1-2 |
| England Super League Women | 2021/04/28 18:30 | Arsenal Women v West Ham Women | W | 2-0 |
| England Super League Women | 2021/04/25 13:00 | Arsenal Women v Brighton & Hove Albion Women | W | 2-0 |
Away History
| UEFA Women's Champions League | 2021/08/18 17:00 | Lokomotiv Moscow Women v PSV Women | W | 1-3 |
| Women’s Friendly | 2021/08/04 12:00 | Wolfsburg Women v PSV Women | L | 2-1 |
| Netherlands Cup Women | 2021/06/05 18:00 | ADO Den Haag Women v PSV Women | W | 0-1 |
| Netherlands Eredivisie Women | 2021/05/30 12:30 | PSV Women v FC Twente Women | W | 2-1 |
| Netherlands Eredivisie Women | 2021/05/23 12:30 | Ajax Women v PSV Women | L | 3-2 |
| Netherlands Eredivisie Women | 2021/05/14 18:00 | PSV Women v ADO Den Haag Women | W | 6-2 |
| Netherlands Eredivisie Women | 2021/05/09 12:30 | ADO Den Haag Women v PSV Women | W | 0-2 |
| Netherlands Eredivisie Women | 2021/05/02 10:15 | FC Twente Women v PSV Women | L | 2-1 |