Head to Head
| Italy Serie A Women | 2021/08/29 18:30 | Sassuolo Women v Fiorentina Women | L | 2-1 |
| Italy Serie A Women | 2021/03/07 13:30 | Sassuolo Women v Fiorentina Women | L | 1-0 |
| Italy Serie A Women | 2020/10/03 13:00 | Fiorentina Women v Sassuolo Women | L | 1-3 |
| Italy Serie A Women | 2020/02/15 13:30 | Fiorentina Women v Sassuolo Women | W | 2-1 |
| Italy Serie A Women | 2019/10/19 13:00 | Sassuolo Women v Fiorentina Women | W | 1-2 |
| Italy Serie A Women | 2019/02/09 13:30 | Fiorentina Women v Sassuolo Women | W | 4-1 |
| Italy Serie A Women | 2018/10/27 13:00 | Sassuolo Women v Fiorentina Women | W | 0-2 |
| Italy Serie A Women | 2018/02/17 13:30 | Fiorentina Women v Sassuolo Women | W | 2-0 |
Home History
| Italy Serie A Women | 2021/12/12 13:30 | Empoli Women v Fiorentina Women | D | 1-1 |
| Italy Serie A Women | 2021/12/04 13:30 | Fiorentina Women v ASD Pomigliano Women | W | 3-1 |
| Italy Serie A Women | 2021/11/13 13:30 | Roma Women v Fiorentina Women | L | 1-0 |
| Italy Serie A Women | 2021/11/06 13:30 | Fiorentina Women v Inter Milan Women | L | 2-3 |
| Italy Serie A Women | 2021/10/31 11:30 | Fiorentina Women v AC Milan Women | L | 0-1 |
| Italy Serie A Women | 2021/10/10 10:30 | Verona Women v Fiorentina Women | W | 1-3 |
| Italy Serie A Women | 2021/10/02 10:30 | Fiorentina Women v Sampdoria Women | W | 4-2 |
| Italy Serie A Women | 2021/09/26 10:30 | Lazio Women v Fiorentina Women | W | 1-6 |
Away History
| Italy Super Cup Women | 2022/01/05 16:30 | Juventus Women v Sassuolo Women | D | 1-1 |
| Italy Serie A Women | 2021/12/11 13:30 | Inter Milan Women v Sassuolo Women | D | 2-2 |
| Italy Serie A Women | 2021/12/04 13:30 | Sassuolo Women v Juventus Women | L | 0-2 |
| Coppa Italia Women | 2021/11/20 13:30 | Cesena Women v Sassuolo Women | W | 0-2 |
| Italy Serie A Women | 2021/11/13 13:30 | Napoli Women v Sassuolo Women | W | 0-1 |
| Italy Serie A Women | 2021/11/07 11:30 | Sassuolo Women v ASD Pomigliano Women | W | 4-2 |
| Italy Serie A Women | 2021/10/31 11:30 | Roma Women v Sassuolo Women | L | 2-0 |
| Italy Serie A Women | 2021/10/10 12:30 | Sassuolo Women v Empoli Women | W | 3-2 |