Home History
| Spain Tercera Group 14 | 2021/10/17 15:00 | Extremadura B v CD Diocesano | W | 0-4 |
| Spain Tercera Group 14 | 2021/10/10 10:00 | CD Diocesano v CD Badajoz B | W | 3-2 |
| Spain Tercera Group 14 | 2021/10/03 10:00 | CD Miajadas v CD Diocesano | W | 0-1 |
| Spain Tercera Group 14 | 2021/09/26 10:00 | CD Diocesano v Olivenza | W | 3-1 |
| Spain Tercera Group 14 | 2021/09/19 10:00 | CD Diocesano v Moralo | L | 0-3 |
| Spain Tercera Group 14 | 2021/09/11 17:00 | AD Llerenense v CD Diocesano | W | 0-2 |
| Europe Friendlies | 2021/08/21 18:00 | CD Diocesano v UD Montijo | L | 0-3 |
| Spain Tercera - Play-Offs | 2021/06/05 17:30 | CD Coria v CD Diocesano | L | 3-1 |
Away History
| Spain Tercera Group 14 | 2021/10/17 16:00 | CD Don Alvaro v AD Llerenense | D | 0-0 |
| Spain Tercera Group 14 | 2021/10/10 10:00 | SP Villafranca v CD Don Alvaro | L | 3-1 |
| Spain Tercera Group 14 | 2021/10/03 16:00 | CD Don Alvaro v CD Azuaga | L | 2-3 |
| Spain Tercera Group 14 | 2021/09/26 10:00 | Calamonte v CD Don Alvaro | W | 1-2 |
| Spain Tercera Group 14 | 2021/09/19 17:00 | CD Don Alvaro v CF Trujillo | W | 2-1 |
| Spain Tercera Group 14 | 2021/09/12 17:00 | Plasencia v CD Don Alvaro | L | 4-1 |
| Europe Friendlies | 2021/08/04 18:30 | CD Don Alvaro v Merida | L | 2-3 |