| Spain Primera Women | 2021/09/25 15:00 | CD Alaves Women v Villarreal Women | L | 2-0 |
| Spain Primera Women | 2021/12/22 16:30 | Real Betis Women v Villarreal Women | W | 0-1 |
| Spain Primera Women | 2021/12/18 15:00 | Villarreal Women v Valencia Women | L | 0-2 |
| Spain Primera Women | 2021/12/12 10:00 | Levante UD Women v Villarreal Women | W | 1-2 |
| Spain Primera Women | 2021/12/04 15:30 | Villarreal Women v Real Madrid Women | L | 0-2 |
| Spain Primera Women | 2021/11/21 12:00 | Rayo Vallecano Women v Villarreal Women | D | 2-2 |
| Spain Primera Women | 2021/11/14 11:00 | Villarreal Women v Sevilla Women | L | 2-3 |
| Spain Primera Women | 2021/11/10 11:00 | Villarreal Women v UDG Tenerife Sur Women | L | 0-2 |
| Spain Primera Women | 2021/11/06 11:00 | Villarreal Women v Madrid CFF Women | L | 0-3 |
| Spain Primera Women | 2021/12/22 16:00 | CD Alaves Women v Real Sociedad Women | L | 0-4 |
| Spain Primera Women | 2021/12/19 16:00 | CD Alaves Women v Levante UD Women | D | 1-1 |
| Spain Primera Women | 2021/12/11 11:00 | Athletic Bilbao Women v CD Alaves Women | L | 4-1 |
| Spain Primera Women | 2021/12/05 11:00 | CD Alaves Women v Valencia Women | W | 3-1 |
| Spain Primera Women | 2021/11/21 17:30 | Real Madrid Women v CD Alaves Women | D | 1-1 |
| Spain Primera Women | 2021/11/14 15:00 | CD Alaves Women v Eibar Women | W | 1-0 |
| Spain Primera Women | 2021/11/06 16:30 | Sevilla Women v CD Alaves Women | L | 1-0 |
| Spain Primera Women | 2021/10/31 11:00 | CD Alaves Women v UDG Tenerife Sur Women | D | 1-1 |