Head to Head
| UEFA Champions League Women | 2021/10/05 19:00 | Barcelona Women v Arsenal Women | L | 4-1 |
| Women’s Friendly | 2019/08/14 18:30 | Arsenal Women v Barcelona Women | L | 2-5 |
Home History
| England FA Cup Women | 2021/12/05 14:00 | Arsenal Women v Chelsea Women | L | 0-3 |
| England Super League Women | 2021/11/21 12:15 | Man Utd Women v Arsenal Women | W | 0-2 |
| UEFA Champions League Women | 2021/11/17 20:00 | Arsenal Women v HB Køge Women | W | 3-0 |
| England Super League Women | 2021/11/13 13:30 | Tottenham Women v Arsenal Women | D | 1-1 |
| UEFA Champions League Women | 2021/11/10 17:45 | HB Køge Women v Arsenal Women | W | 1-5 |
| England Super League Women | 2021/11/07 18:45 | Arsenal Women v West Ham Women | W | 4-0 |
| England FA Cup Women | 2021/10/31 16:45 | Arsenal Women v Brighton & Hove Albion Women | W | 3-0 |
| UEFA Champions League Women | 2021/10/14 19:00 | Arsenal Women v TSG 1899 Hoffenheim Women | W | 4-0 |
Away History
| Spain Primera Women | 2021/12/04 11:00 | Barcelona Women v Athletic Bilbao Women | W | 4-0 |
| Spain Primera Women | 2021/11/20 10:00 | Sevilla Women v Barcelona Women | W | 1-10 |
| UEFA Champions League Women | 2021/11/17 17:45 | TSG 1899 Hoffenheim Women v Barcelona Women | W | 0-5 |
| Spain Primera Women | 2021/11/13 11:00 | Barcelona Women v Levante UD Women | W | 4-0 |
| UEFA Champions League Women | 2021/11/10 17:45 | Barcelona Women v TSG 1899 Hoffenheim Women | W | 4-0 |
| Spain Primera Women | 2021/11/06 11:00 | Eibar Women v Barcelona Women | W | 0-3 |
| Spain Primera Women | 2021/10/31 11:00 | Barcelona Women v Real Sociedad Women | W | 8-1 |
| Spain Primera Women | 2021/10/17 10:00 | Sporting De Huelva Women v Barcelona Women | W | 0-5 |