Head to Head
| Qatar Open Women | 2018/09/20 12:50 | Polina Mikhaylova v Aikaterini Toliou | W | 4-1 |
Home History
| Europe Top 16 Cup Women | 2021/09/18 10:20 | Polina Mikhaylova v Hanna Haponova | L | 1-4 |
| WTT Contender Budapest Women | 2021/08/19 12:00 | Elizabet Abraamian v Polina Mikhaylova | L | 3-0 |
| WTT Contender Budapest Women | 2021/08/18 15:00 | Izabela Lupulesku v Polina Mikhaylova | W | 0-3 |
| WTT Contender Budapest Women | 2021/08/17 12:00 | Tin-Tin Ho v Polina Mikhaylova | W | 0-3 |
| Olympics 2020 - Women | 2021/07/26 03:00 | Polina Mikhaylova v Jia Liu | L | 3-4 |
| Russia Premier League Women | 2021/06/13 13:20 | Polina Mikhaylova v Valeria Shcherbatykh | W | 3-2 |
| Russia Premier League Women | 2021/06/12 14:42 | Polina Mikhaylova v Maria Taylakova | L | 2-3 |
| Russia Premier League Women | 2021/06/12 13:01 | Polina Mikhaylova v Valeria Shcherbatykh | W | 3-2 |
Away History
| European Team Championships Women | 2021/09/28 07:05 | Xia Lian Ni v Aikaterini Toliou | L | 3-0 |
| Europe Top 16 Cup Women | 2021/09/18 11:00 | Georgina Pota v Aikaterini Toliou | L | 4-2 |
| Euro Champs Team Women Quals | 2021/08/28 13:00 | Sibel Altinkaya v Aikaterini Toliou | L | 3-2 |
| Euro Champs Team Women Quals | 2021/08/28 11:00 | Ece Harac v Aikaterini Toliou | W | 1-3 |
| Euro Champs Team Women Quals | 2021/08/27 08:00 | Aikaterini Toliou v Dzana Biogradlic | W | 3-1 |
| Czech Open Women | 2021/08/24 10:10 | Xiaoxin Yang v Aikaterini Toliou | L | 4-0 |
| Czech Open Women | 2021/08/23 09:20 | Nikita Petrovova v Aikaterini Toliou | W | 0-4 |
| European Championships Women | 2021/06/24 15:00 | Aikaterini Toliou v Natalia Bajor | L | 3-4 |