| Portugal Nacional Women | 2021/01/24 15:00 | Benfica Women v Porto Volei Women | L | 3-1 |
| Portugal Nacional Women | 2021/01/16 16:00 | Porto Volei Women v Benfica Women | L | 1-3 |
| Portugal Nacional Women | 2021/10/24 15:00 | SC Espinho Women v Porto Volei Women | W | 0-3 |
| Portugal Nacional Women | 2021/10/17 15:00 | Porto Volei Women v Clube Kairos Women | L | 1-3 |
| Portugal Nacional Women | 2021/10/10 15:00 | Lusofona VC Women v Porto Volei Women | W | 1-3 |
| Portugal Nacional Women | 2021/10/09 16:00 | Porto Volei Women v Sporting CP Women | L | 1-3 |
| Portugal Nacional Women | 2021/10/03 16:00 | CD Aves Women v Porto Volei Women | W | 1-3 |
| Portugal Nacional Women | 2021/04/10 15:00 | Porto Volei Women v AVC Famalicao Women | W | 3-0 |
| Portugal Nacional Women | 2021/04/03 16:00 | AVC Famalicao Women v Porto Volei Women | W | 2-3 |
| Portugal Nacional Women | 2021/03/28 16:00 | Porto Volei Women v CD Aves Women | L | 0-3 |
| Portugal Nacional Women | 2021/10/17 16:00 | Vitoria SC Women v Benfica Women | W | 2-3 |
| Portugal Nacional Women | 2021/10/16 15:30 | FC Porto Women v Benfica Women | L | 3-0 |
| Portugal Nacional Women | 2021/10/10 14:00 | Vilacondense Women v Benfica Women | W | 0-3 |
| Portugal Nacional Women | 2021/10/09 16:00 | Lusofona VC Women v Benfica Women | W | 0-3 |
| Portugal Nacional Women | 2021/10/03 15:00 | Benfica Women v AVC Famalicao Women | W | 3-0 |
| Club Friendlies Women | 2021/09/26 10:00 | Benfica Women v Castelo Maia Women | W | 3-0 |
| Club Friendlies Women | 2021/09/25 19:00 | SC Espinho Women v Benfica Women | W | 0-3 |
| Portugal Nacional Women | 2021/04/10 15:00 | Sporting CP Women v Benfica Women | L | 3-0 |