| Portugal Nacional Women | 2021/10/30 14:00 | Porto Volei Women v Benfica Women | L | 0-3 |
| Portugal Nacional Women | 2021/01/24 15:00 | Benfica Women v Porto Volei Women | L | 3-1 |
| Portugal Nacional Women | 2021/01/16 16:00 | Porto Volei Women v Benfica Women | L | 1-3 |
| Portugal Nacional Women | 2021/12/19 15:00 | Leixoes Women v Porto Volei Women | L | 3-1 |
| Portugal Nacional Women | 2021/12/12 17:00 | Clube Kairos Women v Porto Volei Women | L | 3-2 |
| Portugal Nacional Women | 2021/12/05 16:00 | Vilacondense Women v Porto Volei Women | L | 3-1 |
| Portugal Nacional Women | 2021/11/28 18:00 | Leixoes Women v Porto Volei Women | L | 3-0 |
| Portugal Nacional Women | 2021/11/21 16:00 | Porto Volei Women v Castelo Maia Women | W | 3-0 |
| Portugal Nacional Women | 2021/11/14 15:00 | AVC Famalicao Women v Porto Volei Women | W | 0-3 |
| Portugal Nacional Women | 2021/11/07 13:00 | FC Porto Women v Porto Volei Women | L | 3-0 |
| Portugal Nacional Women | 2021/10/31 16:00 | Porto Volei Women v Boavista FC Women | W | 3-1 |
| Portugal Nacional Women | 2021/12/19 14:30 | Benfica Women v Vilacondense Women | W | 3-2 |
| Portugal Nacional Women | 2021/12/12 19:00 | Benfica Women v Leixoes Women | W | 3-0 |
| Portugal Nacional Women | 2021/12/05 16:00 | SC Espinho Women v Benfica Women | W | 0-3 |
| Portugal Nacional Women | 2021/12/04 16:00 | Benfica Women v Clube Kairos Women | W | 3-0 |
| Portugal Nacional Women | 2021/11/28 16:00 | Benfica Women v Boavista FC Women | W | 3-1 |
| Portugal Nacional Women | 2021/11/21 17:00 | Benfica Women v Sporting CP Women | W | 3-2 |
| Portugal Nacional Women | 2021/11/14 16:00 | Benfica Women v Castelo Maia Women | W | 3-0 |
| Portugal Nacional Women | 2021/11/07 17:00 | CD Aves Women v Benfica Women | W | 0-3 |