Stadium: Grandstand Round: 26 Ground: Hardcourt outdoor
| ATP Rio de Janeiro MD | 2022/02/20 19:00 | Bolelli/Fognini v Gonzalez/Molteni | 7-6,6-2 |
| ATP Rio de Janeiro MD | 2022/02/18 19:30 | Gonzalez/Molteni v Sonego/Vavassori | 7-5,6-4 |
| ATP Rio de Janeiro MD | 2022/02/16 20:50 | Gonzalez/Molteni v Cuevas/Melo | 7-6,6-3 |
| ATP Buenos Aires MD | 2022/02/13 17:00 | Gonzalez/Molteni v Fognini/Zeballos | 6-1,6-1 |
| ATP Buenos Aires MD | 2022/02/11 18:00 | Gonzalez/Molteni v Brkic/Cacic | 7-5,4-6,10-6 |
| ATP Buenos Aires MD | 2022/02/10 18:00 | Sonego/Vavassori v Gonzalez/Molteni | 4-6,1-6 |
| ATP Buenos Aires MD | 2022/02/09 18:10 | Matos/M R Alves v Gonzalez/Molteni | 3-6,4-6 |
| ATP Cordoba MD | 2022/02/06 20:00 | Gonzalez/Molteni v Martin/Weissborn | 7-5,6-3 |