Stadium: Center Court Round: 29 Ground: Clay
| Challenger Vicenza MD | 2022/05/27 09:00 | Barrientos/Reyes-Varela v Comesana/Darderi | 5-7,4-6 |
| Challenger Vicenza MD | 2022/05/25 16:00 | Collarini/Olivo v Comesana/Darderi | 1-6,4-6 |
| Challenger Vicenza MD | 2022/05/27 15:30 | Gigante/Passaro v Bondarevskiy/Prihodko | 7-5,6-4 |
| Challenger Vicenza MD | 2022/05/26 16:00 | Popko/Sachko v Gigante/Passaro | 4-6,6-7 |
| Challenger Vicenza MD | 2022/05/25 12:25 | Gigante/Passaro v Cornea/Tsitsipas | 3-6,6-3,12-10 |