| WTT Contender Lima Women Quals | 2022/06/14 22:00 | Francesca Escobedo v Valentina Rios | W | 1-3 |
| Paraguay Open U21 Women | 2019/09/12 20:15 | Maki Shiomi v Valentina Rios | L | 3-0 |
| Paraguay Open Women | 2019/09/11 19:40 | Ana Codina v Valentina Rios | L | 3-0 |
| Paraguay Open U21 Women | 2019/09/11 15:55 | Panambi Caceres v Valentina Rios | W | 1-3 |
| Paraguay Open Women | 2019/09/10 19:40 | Valentina Rios v Cielo Mutti | W | 3-0 |
| Paraguay Open U21 Women | 2019/09/10 15:10 | Bruna Takahashi v Valentina Rios | L | 3-0 |
| Central American Championships Women | 2019/05/31 00:30 | Paula Medina v Valentina Rios | L | 4-1 |
| Qatar Open XD | 2017/04/28 19:00 | Valentina Rios v Carolina Cardenas | W | 3-0 |
| WTT Feeder Westchester Women | 2022/05/12 23:00 | Madhurika Patkar v Daniely Rios | L | 4-0 |
| World Championship Women | 2021/11/23 18:20 | Zauresh Akasheva v Daniely Rios | L | 4-1 |
| WTT Contender Lasko Women | 2021/11/02 15:45 | Daniely Rios v Lucie Gauthier | L | 0-3 |
| WTT Contender Tunis Women | 2021/10/25 09:00 | Daniely Rios v Filippa Bergand | L | 1-3 |
| Swedish Pro Series Women | 2021/03/25 12:40 | Mie Skov v Daniely Rios | L | 3-0 |
| Swedish Pro Series Women | 2021/03/25 11:20 | Jennifer Jonsson v Daniely Rios | L | 3-2 |
| Swedish Pro Series Women | 2021/03/25 09:00 | Rebecca Muskantor v Daniely Rios | W | 0-3 |
| Swedish Pro Series Women | 2021/03/24 12:00 | Mie Skov v Daniely Rios | L | 3-2 |