Stadium: Centre Court Round: 28 Ground: Grass
| Wimbledon Women WD | 2022/07/06 12:10 | Mertens/Zhang v Guarachi/Klepac | 6-3,6-2 |
| Wimbledon Women WD | 2022/07/04 13:00 | Mertens/Zhang v Kichenok/Olaru | 6-4,6-3 |
| Wimbledon Women WD | 2022/07/02 11:30 | Mertens/Zhang v Golubic/Osorio | 6-3,6-2 |
| Wimbledon Women WD | 2022/06/30 15:05 | Mertens/Zhang v Bondar/Minnen | 6-3,6-1 |
| WTA Birmingham WD | 2022/06/18 15:00 | Mertens/Zhang v Chan/Stosur | 6-1,7-5 |
| WTA Birmingham WD | 2022/06/17 16:30 | Mertens/Zhang v Niculescu/Ruse | 6-2,7-6 |
| WTA Birmingham WD | 2022/06/15 14:15 | Mertens/Zhang v Harrison/Santamaria | 6-2,6-3 |
| WTA Mallorca WD | 2019/06/20 13:00 | Mertens/Zhang v Bencic/Kuzmova | 0-6,2-6 |
| Wimbledon Women WD | 2022/07/06 13:45 | Collins/Krawczyk v Rosolska/Routliffe | 6-1,6-7,6-3 |
| Wimbledon Women WD | 2022/07/03 13:30 | Dabrowski/Olmos v Collins/Krawczyk | 4-6,3-6 |
| Wimbledon Women WD | 2022/07/02 10:00 | Collins/Krawczyk v Bouzkova/Mihalikova | 6-1,6-3 |
| Wimbledon Women WD | 2022/06/29 13:05 | Bara/Gorgodze v Collins/Krawczyk | 3-6,2-6 |
| Australian Open Women WD | 2022/01/24 05:15 | Krejcikova/Siniakova v Collins/Krawczyk | 6-4,6-4 |
| Australian Open Women WD | 2022/01/22 04:25 | Collins/Krawczyk v Muhammad/Pegula | 6-3,7-6 |
| Australian Open Women WD | 2022/01/19 04:00 | Collins/Krawczyk v Kasatkina/Samsonova | 6-3,6-3 |