Stadium: Centre Court Round: 29 Ground: Grass
| Wimbledon Women WD | 2022/07/08 17:00 | Mertens/Zhang v Collins/Krawczyk | 6-2,3-6,6-3 |
| Wimbledon Women WD | 2022/07/06 12:10 | Mertens/Zhang v Guarachi/Klepac | 6-3,6-2 |
| Wimbledon Women WD | 2022/07/04 13:00 | Mertens/Zhang v Kichenok/Olaru | 6-4,6-3 |
| Wimbledon Women WD | 2022/07/02 11:30 | Mertens/Zhang v Golubic/Osorio | 6-3,6-2 |
| Wimbledon Women WD | 2022/06/30 15:05 | Mertens/Zhang v Bondar/Minnen | 6-3,6-1 |
| WTA Birmingham WD | 2022/06/18 15:00 | Mertens/Zhang v Chan/Stosur | 6-1,7-5 |
| WTA Birmingham WD | 2022/06/17 16:30 | Mertens/Zhang v Niculescu/Ruse | 6-2,7-6 |
| WTA Birmingham WD | 2022/06/15 14:15 | Mertens/Zhang v Harrison/Santamaria | 6-2,6-3 |
| Wimbledon Women WD | 2022/07/08 12:30 | Kichenok/Ostapenko v Krejcikova/Siniakova | 2-6,2-6 |
| Wimbledon Women WD | 2022/07/05 10:00 | Melichar-Martinez/Perez v Krejcikova/Siniakova | 6-1,6-7,2-6 |
| Wimbledon Women WD | 2022/07/03 15:05 | Flipkens/Sorribes Tormo v Krejcikova/Siniakova | 6-7,4-6 |
| Wimbledon Women WD | 2022/07/01 14:05 | Kontaveit/Rogers v Krejcikova/Siniakova | 6-7,3-6 |
| Wimbledon Women WD | 2022/06/29 11:30 | Lechemia/Parrizas-Diaz v Krejcikova/Siniakova | 1-6,1-6 |
| WTA Doha WD | 2022/02/22 15:30 | Krejcikova/Siniakova v Eikeri/Panova | 6-2,6-1 |
| Australian Open Women WD | 2022/01/30 04:00 | Krejcikova/Siniakova v Danilina/Haddad Maia | 6-7,6-4,6-4 |
| Australian Open Women WD | 2022/01/27 02:00 | Krejcikova/Siniakova v Kudermetova/Mertens | 6-2,6-3 |