Head to Head
| Spain Primera Women | 2022/01/08 11:00 | Villarreal Women v CD Alaves Women | L | 3-1 |
| Spain Primera Women | 2021/09/25 15:00 | CD Alaves Women v Villarreal Women | W | 2-0 |
Home History
| Spain Primera Women | 2022/09/25 10:00 | Atletico Madrid Women v CD Alaves Women | L | 1-0 |
| Spain Primera Women | 2022/09/17 10:00 | CD Alaves Women v Madrid CFF Women | L | 1-2 |
| Women’s Friendly | 2022/09/04 14:00 | Real Sociedad Women v CD Alaves Women | L | 4-1 |
| Women’s Friendly | 2022/08/28 10:00 | Eibar Women v CD Alaves Women | W | 0-3 |
| Spain Primera Women | 2022/05/15 10:00 | Real Sociedad Women v CD Alaves Women | L | 6-1 |
| Spain Primera Women | 2022/05/07 10:00 | CD Alaves Women v Athletic Bilbao Women | L | 1-3 |
| Spain Primera Women | 2022/05/01 10:00 | Sporting De Huelva Women v CD Alaves Women | L | 2-1 |
| Spain Primera Women | 2022/04/17 09:00 | CD Alaves Women v Real Madrid Women | L | 0-1 |
Away History
| Spain Primera Women | 2022/09/25 15:00 | Villarreal Women v Barcelona Women | L | 1-4 |
| Spain Primera Women | 2022/09/17 14:00 | Real Sociedad Women v Villarreal Women | L | 2-0 |
| Women’s Friendly | 2022/09/03 10:00 | Villarreal Women v Espanyol Women | D | 1-1 |
| Women’s Friendly | 2022/08/12 16:45 | Villarreal Women v Valencia Women | D | 1-1 |
| Spain Primera Women | 2022/05/15 10:00 | Real Madrid Women v Villarreal Women | L | 1-0 |
| Spain Primera Women | 2022/05/08 10:00 | Villarreal Women v Real Betis Women | W | 2-0 |
| Spain Primera Women | 2022/05/01 09:30 | Eibar Women v Villarreal Women | D | 1-1 |
| Spain Primera Women | 2022/04/17 10:00 | Villarreal Women v Sporting De Huelva Women | D | 1-1 |