[16] Villarreal Women 1-0 CD Alaves Women [15] 2023-01-28 11:00
Stadium: Estadio de la Ceramica Round: 17
Head to Head
| Spain Primera Women | 2022/10/01 10:00 | CD Alaves Women v Villarreal Women | W | 0-4 |
| Spain Primera Women | 2022/01/08 11:00 | Villarreal Women v CD Alaves Women | W | 3-1 |
| Spain Primera Women | 2021/09/25 15:00 | CD Alaves Women v Villarreal Women | L | 2-0 |
Home History
| Spain Primera Women | 2023/01/24 20:00 | Valencia Women v Villarreal Women | L | 2-0 |
| Spain Primera Women | 2023/01/14 15:00 | Atletico Madrid Women v Villarreal Women | D | 2-2 |
| Spain Copa De La Reina | 2023/01/10 17:45 | Villarreal Women v Sevilla Women | L | 0-1 |
| Spain Primera Women | 2023/01/07 11:00 | Villarreal Women v Levante UD Women | L | 0-6 |
| Spain Primera Women | 2022/12/17 11:00 | Levante Las Planas Women v Villarreal Women | D | 2-2 |
| Spain Primera Women | 2022/12/11 11:00 | Villarreal Women v Sporting De Huelva Women | L | 2-3 |
| Spain Primera Women | 2022/12/04 15:00 | Alhama CF Women v Villarreal Women | W | 0-1 |
| Spain Primera Women | 2022/11/26 15:00 | Villarreal Women v Athletic Bilbao Women | L | 1-6 |
Away History
| Spain Primera Women | 2023/01/25 18:00 | CD Alaves Women v Real Madrid Women | L | 1-3 |
| Spain Primera Women | 2023/01/14 11:00 | Levante Las Planas Women v CD Alaves Women | L | 1-0 |
| Spain Copa De La Reina | 2023/01/10 17:45 | Granada CF Women v CD Alaves Women | L | 1-0 |
| Spain Primera Women | 2023/01/07 11:00 | CD Alaves Women v Valencia Women | W | 4-1 |
| Spain Primera Women | 2022/12/17 17:15 | Alhama CF Women v CD Alaves Women | L | 3-1 |
| Spain Primera Women | 2022/12/11 11:00 | CD Alaves Women v Sevilla Women | W | 2-0 |
| Spain Primera Women | 2022/12/04 11:00 | Sporting De Huelva Women v CD Alaves Women | D | 2-2 |
| Spain Primera Women | 2022/11/27 11:00 | CD Alaves Women v Real Betis Women | W | 3-1 |