[1] Villarreal 5-0 FK Austria Vienna [4] 2022-10-06 19:00
Stadium: Estadio de la Ceramica Round: 3
Referee: Jochem Kamphuis Home Manager: Unai Emery Away Manager: Manfred Schmid
Home History
| Spain La Liga | 2022/10/01 12:00 | Cadiz v Villarreal | D | 0-0 |
| Spain La Liga | 2022/09/18 14:15 | Villarreal v Sevilla | D | 1-1 |
| UEFA Conference League | 2022/09/15 19:00 | Hapoel Beer Sheva v Villarreal | W | 1-2 |
| Spain La Liga | 2022/09/11 19:00 | Real Betis v Villarreal | L | 1-0 |
| UEFA Conference League | 2022/09/08 16:45 | Villarreal v Lech Poznan | W | 4-3 |
| Spain La Liga | 2022/09/04 16:30 | Villarreal v Elche | W | 4-0 |
| Spain La Liga | 2022/08/28 15:30 | Getafe v Villarreal | D | 0-0 |
| UEFA Conference League Qualifying | 2022/08/25 19:00 | Hajduk Split v Villarreal | W | 0-2 |
Away History
| Austria Bundesliga | 2022/10/02 15:00 | FK Austria Vienna v SK Sturm Graz | L | 0-3 |
| Austria Bundesliga | 2022/09/18 12:30 | FK Austria Vienna v SV Ried | W | 3-0 |
| UEFA Conference League | 2022/09/15 19:00 | Lech Poznan v FK Austria Vienna | L | 4-1 |
| Austria Bundesliga | 2022/09/11 12:30 | Hartberg v FK Austria Vienna | W | 0-3 |
| UEFA Conference League | 2022/09/08 16:45 | FK Austria Vienna v Hapoel Beer Sheva | D | 0-0 |
| Austria Bundesliga | 2022/09/03 15:00 | FK Austria Vienna v Austria Lustenau | D | 2-2 |
| Austria Cup | 2022/08/31 18:30 | ASV Siegendorf v FK Austria Vienna | W | 0-5 |
| Austria Bundesliga | 2022/08/28 15:00 | Austria Klagenfurt v FK Austria Vienna | D | 3-3 |