Stadium: Court 3 Round: 62 Ground: Clay
| ITF M25 Denia | 2022/07/25 14:00 | Aristotelis Thanos v Alvaro Peiro Serrano | 6-3,4-6,10-0 |
| ITF M25 Getxo | 2022/07/03 08:00 | Alvaro Peiro Serrano v Noel Larwig | 3-6,4-6 |
| ITF M25 La Nucia | 2022/05/29 11:30 | Emiliano Jorquera v Alvaro Peiro Serrano | 5-7,6-3,10-5 |
| ITF M25 Vic | 2022/05/15 08:00 | Esteban B Munoz v Alvaro Peiro Serrano | 0-6,3-6 |
| ITF M25 Denia | 2022/07/27 16:40 | Samuel M Arjona v Vicente O Moratalla | 4-6,4-6 |
| ITF M25 Gandia | 2022/07/20 15:50 | Philip Sekulic v Samuel M Arjona | 6-2,6-1 |
| ITF M25 Getxo | 2022/07/03 13:30 | Alejandro Garcia v Samuel M Arjona | 6-2,6-1 |
| ITF M25 Bakio | 2022/06/27 10:40 | James Mackinlay v Samuel M Arjona | 3-6,6-4,11-9 |
| ITF M15 Monastir | 2022/05/29 10:00 | Jinpeng Tang v Samuel M Arjona | 6-3,6-3 |
| ITF M25 Monastir | 2022/05/25 11:45 | Samuel M Arjona v Matheus C Bueres | 4-6,2-6 |
| ITF M25 Monastir | 2022/05/23 12:30 | Samuel M Arjona v Shivank Bhatnagar | 7-6,3-6,10-7 |
| ITF M25 Monastir | 2022/05/15 08:00 | Samuel M Arjona v Karan Singh | 6-7,1-6 |