[13] Villarreal Women 0-4 Real Madrid Women [5] 2022-11-03 17:45
Stadium: Estadio de la Ceramica Round: 1
Head to Head
| Spain Primera Women | 2022/05/15 10:00 | Real Madrid Women v Villarreal Women | L | 1-0 |
| Spain Primera Women | 2021/12/04 15:30 | Villarreal Women v Real Madrid Women | L | 0-2 |
Home History
| Spain Primera Women | 2022/10/30 15:00 | Villarreal Women v Valencia Women | D | 1-1 |
| Spain Primera Women | 2022/10/23 10:00 | UDG Tenerife Sur Women v Villarreal Women | L | 2-0 |
| Spain Primera Women | 2022/10/16 10:00 | Villarreal Women v Sevilla Women | L | 0-5 |
| Spain Primera Women | 2022/10/01 10:00 | CD Alaves Women v Villarreal Women | W | 0-4 |
| Spain Primera Women | 2022/09/25 15:00 | Villarreal Women v Barcelona Women | L | 1-4 |
| Spain Primera Women | 2022/09/17 14:00 | Real Sociedad Women v Villarreal Women | L | 2-0 |
| Women’s Friendly | 2022/09/03 10:00 | Villarreal Women v Espanyol Women | D | 1-1 |
| Women’s Friendly | 2022/08/12 16:45 | Villarreal Women v Valencia Women | D | 1-1 |
Away History
| Spain Primera Women | 2022/10/30 18:00 | Real Madrid Women v Sevilla Women | W | 2-0 |
| UEFA Women's Champions League | 2022/10/26 16:45 | Real Madrid Women v PSG Women | D | 0-0 |
| Spain Primera Women | 2022/10/23 09:00 | Levante UD Women v Real Madrid Women | D | 2-2 |
| UEFA Women's Champions League | 2022/10/20 16:45 | KS Vllaznia Women v Real Madrid Women | W | 0-2 |
| Spain Primera Women | 2022/10/16 10:00 | Real Madrid Women v CD Alaves Women | W | 7-1 |
| Spain Primera Women | 2022/10/02 16:00 | Athletic Bilbao Women v Real Madrid Women | W | 0-3 |
| UEFA Women's Champions League | 2022/09/28 18:00 | Real Madrid Women v Rosenborg Women | W | 2-1 |
| UEFA Women's Champions League | 2022/09/21 16:00 | Rosenborg Women v Real Madrid Women | W | 0-3 |