Away History
| Champions League Women | 2022/12/04 09:45 | Maria Xiao v Tania Plaian | W | 3-1 |
| Champions League Women | 2022/12/02 18:45 | Nina Mittelham v Maria Xiao | W | 2-3 |
| Champions League Women | 2022/12/02 18:00 | Xiaona Shan v Maria Xiao | W | 0-3 |
| Champions League Women | 2022/11/29 17:20 | Maria Xiao v Ho Ching Lee | W | 3-1 |
| WTT Feeder Dusseldorf Women | 2022/11/23 15:25 | Maria Xiao v Hyobin Yoon | L | 2-3 |
| Champions League Women | 2022/11/09 16:55 | Andreea Dragoman v Maria Xiao | W | 1-3 |
| WTT Contender Novo Gorica Women | 2022/11/01 18:00 | Maria Xiao v Camille Lutz | L | 2-3 |
| WTT Contender Novo Gorica Women | 2022/11/01 08:30 | Maria Xiao v Magdalena Sikorska | W | 3-0 |