Head to Head
| UEFA Europa League | 2016/02/25 20:05 | Napoli v Villarreal | D | 1-1 |
| UEFA Europa League | 2016/02/18 18:00 | Villarreal v Napoli | L | 1-0 |
Home History
| Club Friendly List | 2022/12/11 15:00 | Napoli v Crystal Palace | W | 3-1 |
| Europe Friendlies | 2022/12/07 17:45 | Antalyaspor v Napoli | W | 2-3 |
| Italy Serie A | 2022/11/12 14:00 | Napoli v Udinese | W | 3-2 |
| Italy Serie A | 2022/11/08 17:30 | Napoli v Empoli | W | 2-0 |
| Italy Serie A | 2022/11/05 17:00 | Atalanta v Napoli | W | 1-2 |
| UEFA Champions League | 2022/11/01 20:00 | Liverpool v Napoli | L | 2-0 |
| Italy Serie A | 2022/10/29 13:00 | Napoli v Sassuolo | W | 4-0 |
| UEFA Champions League | 2022/10/26 19:00 | Napoli v Rangers | W | 3-0 |
Away History
| Elite Club Friendlies | 2022/12/15 20:00 | Aston Villa v Villarreal | W | 0-1 |
| Europe Friendlies | 2022/12/06 17:00 | Galatasaray v Villarreal | W | 3-4 |
| Europe Friendlies | 2022/12/03 16:00 | Fenerbahce v Villarreal | L | 2-1 |
| Spain Copa del Rey | 2022/11/12 20:00 | Santa Amalia v Villarreal | W | 0-9 |
| Spain La Liga | 2022/11/09 19:00 | Espanyol v Villarreal | W | 0-1 |
| Spain La Liga | 2022/11/06 17:30 | Villarreal v Mallorca | L | 0-2 |
| UEFA Conference League | 2022/11/03 20:00 | Lech Poznan v Villarreal | L | 3-0 |
| Spain La Liga | 2022/10/30 17:30 | Athletic Bilbao v Villarreal | L | 1-0 |