| Portugal Nacional Women | 2022/12/11 14:30 | FC Porto Women v Benfica Women | W | 3-0 |
| Portugal Nacional Women | 2022/11/13 15:00 | Benfica Women v FC Porto Women | W | 0-3 |
| Portugal Nacional Women | 2022/04/09 14:00 | FC Porto Women v Benfica Women | W | 3-0 |
| Portugal Nacional Women | 2022/04/03 18:00 | Benfica Women v FC Porto Women | L | 3-2 |
| Portugal Nacional Women | 2022/04/02 19:00 | Benfica Women v FC Porto Women | W | 2-3 |
| Portugal Nacional Women | 2022/03/27 16:00 | FC Porto Women v Benfica Women | W | 3-2 |
| Portugal Nacional Women | 2022/03/13 14:00 | FC Porto Women v Benfica Women | L | 0-3 |
| Portugal Nacional Women | 2022/02/10 20:30 | Benfica Women v FC Porto Women | L | 3-1 |
| Challenge Cup Women | 2023/02/01 18:00 | Stara Pazova Women v FC Porto Women | L | 3-0 |
| Portugal Nacional Women | 2023/01/29 16:00 | FC Porto Women v Leixoes Women | W | 3-1 |
| Portugal Nacional Women | 2023/01/28 15:00 | Vilacondense Women v FC Porto Women | W | 0-3 |
| Portugal Nacional Women | 2023/01/22 16:00 | Porto Volei Women v FC Porto Women | W | 1-3 |
| Challenge Cup Women | 2023/01/18 15:00 | Rapid Bucuresti Women v FC Porto Women | W | 11-15 |
| Portugal Nacional Women | 2023/01/15 17:30 | FC Porto Women v Sporting CP Women | L | 0-3 |
| Challenge Cup Women | 2023/01/12 20:00 | FC Porto Women v Rapid Bucuresti Women | W | 3-2 |
| Portugal Nacional Women | 2023/01/08 16:00 | FC Porto Women v Clube Kairos Women | W | 3-2 |
| Portugal Nacional Women | 2023/01/29 15:00 | Benfica Women v Porto Volei Women | W | 3-0 |
| Portugal Nacional Women | 2023/01/28 15:00 | Leixoes Women v Benfica Women | L | 3-0 |
| Portugal Nacional Women | 2023/01/22 16:30 | Benfica Women v Vitoria SC Women | W | 3-2 |
| Portugal Nacional Women | 2023/01/14 20:00 | Benfica Women v Vilacondense Women | W | 3-0 |
| Portugal Nacional Women | 2023/01/08 15:00 | Sporting CP Women v Benfica Women | W | 1-3 |
| Portugal Nacional Women | 2023/01/07 16:00 | Benfica Women v Clube Kairos Women | L | 1-3 |
| Portugal Nacional Women | 2022/12/18 16:00 | Porto Volei Women v Benfica Women | W | 2-3 |
| Portugal Nacional Women | 2022/12/11 14:30 | FC Porto Women v Benfica Women | L | 3-0 |