[2] Roma Women 0-1 Barcelona Women [1] 2023-03-21 20:00
Stadium: Stadio Tre Fontane Round: 3
Referee: Iuliana Elena Demetrescu Home Manager: Alessandro Spugna Away Manager: Jonatan Giraldez
Home History
| Italy Serie A Women | 2023/03/17 17:00 | Fiorentina Women v Roma Women | W | 1-5 |
| Coppa Italia Women | 2023/03/11 13:30 | Roma Women v AC Milan Women | W | 3-1 |
| Coppa Italia Women | 2023/03/05 13:00 | AC Milan Women v Roma Women | L | 1-0 |
| Italy Serie A Women | 2023/02/26 11:30 | Sampdoria Women v Roma Women | W | 0-1 |
| Italy Serie A Women | 2023/02/11 13:30 | Roma Women v Inter Milan Women | W | 3-2 |
| Coppa Italia Women | 2023/02/08 13:30 | Roma Women v ASD Pomigliano Women | W | 2-0 |
| Italy Serie A Women | 2023/02/04 11:30 | Como Women v Roma Women | W | 0-1 |
| Italy Serie A Women | 2023/01/29 13:30 | Roma Women v Sassuolo Women | W | 5-0 |
Away History
| Spain Primera Women | 2023/03/17 18:00 | Barcelona Women v Valencia Women | W | 5-1 |
| Spain Primera Women | 2023/03/11 17:15 | Levante UD Women v Barcelona Women | W | 0-4 |
| Spain Primera Women | 2023/03/05 11:00 | Barcelona Women v Villarreal Women | W | 5-0 |
| Spain Primera Women | 2023/02/11 17:15 | CD Alaves Women v Barcelona Women | W | 0-4 |
| Spain Primera Women | 2023/02/05 15:00 | Barcelona Women v Real Betis Women | W | 7-0 |
| Spain Primera Women | 2023/02/01 18:00 | Valencia Women v Barcelona Women | W | 0-4 |
| Spain Primera Women | 2023/01/29 17:00 | UDG Tenerife Sur Women v Barcelona Women | W | 0-6 |
| Spain Primera Women | 2023/01/25 17:00 | Barcelona Women v Levante Las Planas Women | W | 7-0 |