| WTT Contender Tunis XD | 2021/10/27 18:00 | Piccolin/Stoyanov v Robles/Xiao | W | 0-3 |
| WTT Contender Doha XD | 2021/03/04 15:15 | Piccolin/Stoyanov v Robles/Xiao | W | 1-3 |
| WTT Contender Amman XD | 2023/02/09 07:00 | Duda/Wan v Robles/Xiao | L | 3-0 |
| WTT Contender Doha XD | 2023/01/19 07:00 | Robles/Xiao v Gnanasekaran/Batra | L | 0-3 |
| WTT Contender Doha XD | 2023/01/18 07:30 | Diaconu/Pletea v Robles/Xiao | W | 2-3 |
| WTT Feeder Fort Lauderdale XD | 2022/12/14 01:30 | Robles/Xiao v Balazova/Pistej | L | 1-3 |
| WTT Feeder Fort Lauderdale XD | 2022/12/13 01:30 | Robles/Xiao v Oyebode/Schreiner | W | 3-0 |
| WTT Feeder Fort Lauderdale XD | 2022/12/12 15:30 | Robles/Xiao v Yu/Guo | W | 3-0 |
| WTT Feeder Dusseldorf XD | 2022/11/24 16:10 | Robles/Xiao v Cho/Lee | L | 1-3 |
| WTT Feeder Dusseldorf XD | 2022/11/24 09:00 | Robles/Xiao v Paredes/Mino | W | 2-1 |
| WTT Contender Doha XD Quals | 2023/01/16 17:50 | Diaconu/Pletea v Piccolin/Stoyanov | L | 3-1 |
| WTT Contender Novo Gorica XD | 2022/11/03 13:00 | Piccolin/Stoyanov v Diaconu/Pletea | L | 0-3 |
| WTT Feeder Panagyurishte XD | 2022/09/02 06:30 | Krastev/Yovkova v Piccolin/Stoyanov | L | 3-0 |
| WTT Feeder Olomouc XD | 2022/08/25 08:35 | Chen/Mischek v Piccolin/Stoyanov | L | 3-1 |
| European Championships XD | 2022/08/14 08:05 | Piccolin/Stoyanov v Ni/Mladenovic | L | 2-3 |
| WTT Feeder Westchester XD | 2022/05/12 14:00 | Piccolin/Laurenti v Piccolin/Stoyanov | L | 3-2 |
| World Championship XD | 2021/11/25 16:10 | Doo/Wong v Piccolin/Stoyanov | L | 3-0 |
| World Championship XD | 2021/11/23 22:00 | Piccolin/Stoyanov v Gomez/Ortega | W | 3-0 |