| ITTF Pan American Championships Women | 2022/11/03 20:15 | Valentina Rios v Mo Zhang | L | 0-4 |
| ITTF South American Champs Women | 2022/07/24 23:00 | Valentina Rios v Candela Molero | W | 3-1 |
| WTT Contender Lima Women | 2022/06/16 16:15 | Valentina Rios v Miyu Nagasaki | L | 0-3 |
| WTT Contender Lima Women Quals | 2022/06/15 21:30 | Valentina Rios v Daniely Rios | W | 2-0 |
| WTT Contender Lima Women Quals | 2022/06/14 22:00 | Francesca Escobedo v Valentina Rios | W | 1-3 |
| Paraguay Open U21 Women | 2019/09/12 20:15 | Maki Shiomi v Valentina Rios | L | 3-0 |
| Paraguay Open Women | 2019/09/11 19:40 | Ana Codina v Valentina Rios | L | 3-0 |
| Paraguay Open U21 Women | 2019/09/11 15:55 | Panambi Caceres v Valentina Rios | W | 1-3 |