[11] Villarreal 3-4 Barcelona [6] 2023-08-27 15:30
Stadium: Estadio de la Ceramica Round: 3
Referee: Alejandro Jose Hernandez Hernandez Home Manager: Quique Setien Away Manager: Xavi
Head to Head
| Spain La Liga | 2023/02/12 20:00 | Villarreal v Barcelona | L | 0-1 |
| Spain La Liga | 2022/10/20 19:00 | Barcelona v Villarreal | L | 3-0 |
| Spain La Liga | 2022/05/22 20:00 | Barcelona v Villarreal | W | 0-2 |
| Spain La Liga | 2021/11/27 20:00 | Villarreal v Barcelona | L | 1-3 |
| Spain La Liga | 2021/04/25 14:15 | Villarreal v Barcelona | L | 1-2 |
| Spain La Liga | 2020/09/27 19:00 | Barcelona v Villarreal | L | 4-0 |
| Spain La Liga | 2020/07/05 20:00 | Villarreal v Barcelona | L | 1-4 |
| Spain La Liga | 2019/09/24 19:00 | Barcelona v Villarreal | L | 2-1 |
Home History
| Spain La Liga | 2023/08/18 17:30 | Mallorca v Villarreal | W | 0-1 |
| Spain La Liga | 2023/08/13 17:30 | Villarreal v Real Betis | L | 1-2 |
| Elite Club Friendlies | 2023/08/06 15:00 | Newcastle v Villarreal | L | 4-0 |
| Elite Club Friendlies | 2023/08/05 11:30 | Nice v Villarreal | D | 1-1 |
| Europe Friendlies | 2023/07/30 19:00 | Sporting v Villarreal | L | 3-0 |
| Europe Friendlies | 2023/07/27 17:00 | Feyenoord v Villarreal | D | 1-1 |
| Europe Friendlies | 2023/07/22 12:00 | Hannover 96 v Villarreal | L | 3-0 |
| Europe Friendlies | 2023/07/18 17:30 | SCR Altach v Villarreal | W | 0-3 |
Away History
| Spain La Liga | 2023/08/20 17:30 | Barcelona v Cadiz | W | 2-0 |
| Spain La Liga | 2023/08/13 19:30 | Getafe v Barcelona | D | 0-0 |
| Elite Club Friendlies | 2023/08/08 18:00 | Barcelona v Tottenham | W | 4-2 |
| Elite Club Friendlies | 2023/08/02 03:00 | AC Milan v Barcelona | W | 0-1 |
| Elite Club Friendlies | 2023/07/29 21:00 | Barcelona v Real Madrid | W | 3-0 |
| Elite Club Friendlies | 2023/07/27 02:30 | Arsenal v Barcelona | L | 5-3 |
| Elite Club Friendlies | 2023/06/06 10:30 | Vissel Kobe v Barcelona | W | 0-2 |
| Spain La Liga | 2023/06/04 19:00 | Celta Vigo v Barcelona | L | 2-1 |