Head to Head
| Netherlands Cup Women | 2023/05/22 17:00 | PSV Women v Ajax Women | L | 1-3 |
| Netherlands Cup Women | 2023/05/14 12:30 | Ajax Women v PSV Women | L | 5-2 |
| Netherlands Eredivisie Women | 2023/02/05 11:15 | PSV Women v Ajax Women | L | 1-2 |
| Netherlands Eredivisie Women | 2022/11/20 11:15 | Ajax Women v PSV Women | L | 1-0 |
| Netherlands Cup Women | 2022/05/29 12:30 | Ajax Women v PSV Women | L | 3-0 |
| Netherlands Cup Women | 2022/05/26 12:30 | PSV Women v Ajax Women | L | 0-2 |
| Netherlands Cup Women | 2022/04/18 12:30 | Ajax Women v PSV Women | L | 2-1 |
| Netherlands Eredivisie Women | 2022/03/27 10:15 | Ajax Women v PSV Women | D | 0-0 |
Home History
| Netherlands Eredivisie Women | 2023/11/25 13:00 | Heerenveen Women v PSV Women | W | 1-3 |
| Netherlands Eredivisie Women | 2023/11/17 18:30 | Feyenoord Women v PSV Women | W | 0-2 |
| Netherlands Eredivisie Women | 2023/11/10 18:30 | PSV Women v FC Twente Women | L | 1-2 |
| Netherlands Eredivisie Women | 2023/11/05 13:30 | Excelsior Barendrecht Women v PSV Women | D | 1-1 |
| Netherlands Eredivisie Women | 2023/10/20 17:30 | PSV Women v FC Utrecht Women | W | 4-0 |
| Netherlands Eredivisie Women | 2023/10/14 12:00 | Fortuna Sittard Women v PSV Women | L | 1-0 |
| Netherlands Eredivisie Women | 2023/10/06 17:30 | PEC Zwolle Women v PSV Women | L | 2-0 |
| Netherlands Eredivisie Women | 2023/10/01 10:15 | PSV Women v AZ Women | W | 5-1 |
Away History
| Netherlands Eredivisie Women | 2023/11/26 11:15 | AZ Women v Ajax Women | W | 1-2 |
| UEFA Champions League Women | 2023/11/23 20:00 | Roma Women v Ajax Women | L | 3-0 |
| Netherlands Eredivisie Women | 2023/11/19 11:15 | Ajax Women v FC Twente Women | L | 0-1 |
| UEFA Champions League Women | 2023/11/15 20:00 | Ajax Women v PSG Women | W | 2-0 |
| Netherlands Eredivisie Women | 2023/11/10 18:30 | PEC Zwolle Women v Ajax Women | W | 1-3 |
| Netherlands Eredivisie Women | 2023/11/05 11:15 | Ajax Women v FC Utrecht Women | W | 5-2 |
| Netherlands Eredivisie Women | 2023/10/22 10:15 | Fortuna Sittard Women v Ajax Women | W | 0-4 |
| UEFA Champions League Qualifying Women | 2023/10/18 17:00 | Ajax Women v FC Zurich Women | W | 2-0 |