| WTT Star Contender Ljubljana XD Quals | 2023/07/03 07:45 | Huang/Li v Piccolin/Stoyanov | L | 3-1 |
| ITTF World Championships XD | 2023/05/20 08:00 | Piccolin/Stoyanov v Lin/Chen | L | 1-3 |
| WTT Star Contender Bangkok XD Quals | 2023/04/23 02:35 | Hang Lam/Zhu v Piccolin/Stoyanov | L | 3-1 |
| WTT Feeder Dusseldorf XD | 2023/02/15 09:00 | Robles/Xiao v Piccolin/Stoyanov | L | 3-2 |
| WTT Contender Doha XD Quals | 2023/01/16 17:50 | Diaconu/Pletea v Piccolin/Stoyanov | L | 3-1 |
| WTT Contender Novo Gorica XD | 2022/11/03 13:00 | Piccolin/Stoyanov v Diaconu/Pletea | L | 0-3 |
| WTT Feeder Panagyurishte XD | 2022/09/02 06:30 | Krastev/Yovkova v Piccolin/Stoyanov | L | 3-0 |
| WTT Feeder Olomouc XD | 2022/08/25 08:35 | Chen/Mischek v Piccolin/Stoyanov | L | 3-1 |
| WTT Feeder Panagyurishte XD Quals | 2023/08/29 12:05 | Sariev/Hasanova v Bekir/Georgieva | W | 0-3 |
| European Youth Champs XD | 2023/07/20 13:00 | Bekir/Georgieva v Szantosi/Pinto | L | 0-3 |