Head to Head
| Spain Primera Women | 2023/01/28 11:00 | Villarreal Women v CD Alaves Women | W | 1-0 |
| Spain Primera Women | 2022/10/01 10:00 | CD Alaves Women v Villarreal Women | W | 0-4 |
| Spain Primera Women | 2022/01/08 11:00 | Villarreal Women v CD Alaves Women | W | 3-1 |
| Spain Primera Women | 2021/09/25 15:00 | CD Alaves Women v Villarreal Women | L | 2-0 |
Home History
| Spain Primera Federacion Women | 2024/09/15 16:00 | Getafe Women v Villarreal Women | W | 0-1 |
| Women’s Friendly | 2024/08/21 17:00 | Valencia Women v Villarreal Women | L | 2-0 |
| Women’s Friendly | 2024/08/18 17:00 | Levante UD Women v Villarreal Women | L | 1-0 |
| Women’s Friendly | 2024/08/15 17:00 | Seccio Esportiva AEM Women v Villarreal Women | L | 3-0 |
| Spain Primera Women | 2024/06/15 10:00 | Atletico Madrid Women v Villarreal Women | L | 1-0 |
| Spain Primera Women | 2024/06/09 18:30 | Villarreal Women v Sporting De Huelva Women | W | 2-0 |
| Spain Primera Women | 2024/05/25 10:00 | Levante UD Women v Villarreal Women | L | 2-1 |
| Spain Primera Women | 2024/05/10 16:30 | Villarreal Women v Eibar Women | D | 1-1 |
Away History
| Spain Copa De La Reina | 2024/09/11 18:00 | Bizkerre Women v CD Alaves Women | W | 0-4 |
| Spain Primera Federacion Women | 2024/09/07 09:30 | Atletico Madrid Women B v CD Alaves Women | W | 0-1 |
| Women’s Friendly | 2024/08/17 16:00 | CD Alaves Women v Osasuna Women | L | 0-2 |
| Spain Primera Federacion Women | 2024/04/27 17:30 | Alhama CF Women v CD Alaves Women | L | 2-1 |
| Spain Primera Federacion Women | 2024/04/21 10:00 | CD Alaves Women v CE Europa Women | W | 4-0 |
| Spain Primera Federacion Women | 2024/03/30 11:30 | CD Alaves Women v Espanyol Women | D | 0-0 |
| Spain Primera Federacion Women | 2024/03/23 11:00 | Cacereno Women v CD Alaves Women | L | 2-0 |
| Spain Primera Federacion Women | 2024/03/16 11:30 | CD Alaves Women v Seccio Esportiva AEM Women | D | 1-1 |