[5] Villarreal 0-1 Rayo Vallecano [9] 2023-01-30 20:00
Stadium: Estadio de la Ceramica Round: 19
Referee: Juan Luis Pulido Santana Home Manager: Quique Setien Away Manager: Andoni Iraola
Head to Head
| Spain La Liga | 2022/05/12 18:00 | Rayo Vallecano v Villarreal | W | 1-5 |
| Spain La Liga | 2021/12/12 13:00 | Villarreal v Rayo Vallecano | W | 2-0 |
| Spain Copa del Rey | 2020/01/29 18:00 | Rayo Vallecano v Villarreal | W | 0-2 |
| Spain La Liga | 2019/03/17 17:30 | Villarreal v Rayo Vallecano | W | 3-1 |
| Spain La Liga | 2018/11/11 17:30 | Rayo Vallecano v Villarreal | D | 2-2 |
| Spain La Liga | 2016/04/17 16:15 | Rayo Vallecano v Villarreal | L | 2-1 |
| Spain La Liga | 2015/12/06 15:00 | Villarreal v Rayo Vallecano | W | 2-1 |
| Spain La Liga | 2015/02/15 18:00 | Rayo Vallecano v Villarreal | L | 2-0 |
| Spain La Liga | 2014/09/21 15:00 | Villarreal v Rayo Vallecano | W | 4-2 |