Head to Head
| Euro Champs Qualification Women | 2022/08/28 16:00 | Ukraine Women v Portugal Women | L | 3-0 |
| Euro Champs Qualification Women | 2021/05/15 11:30 | Portugal Women v Ukraine Women | L | 0-3 |
| Euro Champs Qualification Women | 2021/05/07 18:00 | Portugal Women v Ukraine Women | L | 1-3 |
| Euro Champs Women | 2019/08/29 16:00 | Portugal Women v Ukraine Women | L | 0-3 |
| CEV Golden European League Women | 2018/05/30 14:00 | Ukraine Women v Portugal Women | L | 3-1 |
| CEV Golden European League Women | 2018/05/27 16:00 | Portugal Women v Ukraine Women | L | 0-3 |