[3] Real Madrid Women 1-0 Villarreal Women [16] 2023-10-07 18:30
Stadium: Ciudad Real Madrid Round: 4
Head to Head
| Spain Primera Women | 2023/04/23 16:00 | Real Madrid Women v Villarreal Women | W | 2-1 |
| Spain Copa De La Reina | 2023/03/09 20:00 | Villarreal Women v Real Madrid Women | D | 1-1 |
| Spain Primera Women | 2022/11/03 17:45 | Villarreal Women v Real Madrid Women | W | 0-4 |
| Spain Primera Women | 2022/05/15 10:00 | Real Madrid Women v Villarreal Women | W | 1-0 |
| Spain Primera Women | 2021/12/04 15:30 | Villarreal Women v Real Madrid Women | W | 0-2 |