Stadium: Stade du Pays de Charleroi Round: 16
| Belgium Super League Women | 2023/11/03 19:30 | KV Mechelen Women v Charleroi Women | L | 4-2 |
| Belgium Super League Women | 2023/05/13 12:00 | KV Mechelen Women v Charleroi Women | L | 2-0 |
| Belgium Super League Women | 2023/03/31 18:00 | Charleroi Women v KV Mechelen Women | L | 0-3 |
| Belgium Super League Women | 2022/12/17 15:00 | KV Mechelen Women v Charleroi Women | D | 1-1 |
| Belgium Super League Women | 2022/08/12 18:00 | Charleroi Women v KV Mechelen Women | L | 0-1 |