| Portugal Nacional Women | 2021/10/16 15:30 | FC Porto Women v Benfica Women | L | 3-0 |
| Portugal Nacional Women | 2021/03/22 17:30 | FC Porto Women v Benfica Women | L | 3-1 |
| Portugal Nacional Women | 2021/03/21 17:00 | FC Porto Women v Benfica Women | L | 3-1 |
| Portugal Nacional Women | 2021/03/18 20:30 | Benfica Women v FC Porto Women | L | 0-3 |
| Portugal Nacional Women | 2021/02/07 15:00 | Benfica Women v FC Porto Women | L | 1-3 |
| Portugal Cup Women | 2021/01/30 15:00 | Benfica Women v FC Porto Women | L | 0-3 |
| Portugal Nacional Women | 2020/10/04 14:00 | FC Porto Women v Benfica Women | W | 2-3 |
| Portugal Nacional Women | 2022/02/06 18:00 | Benfica Women v Vitoria SC Women | W | 3-0 |
| Portugal Nacional Women | 2022/01/23 17:00 | Clube Kairos Women v Benfica Women | W | 2-3 |
| Portugal Nacional Women | 2022/01/16 15:00 | Vitoria SC Women v Benfica Women | W | 1-3 |
| Portugal Nacional Women | 2022/01/09 20:45 | Benfica Women v Sporting CP Women | L | 2-3 |
| Portugal Nacional Women | 2022/01/08 17:00 | Porto Volei Women v Benfica Women | L | 3-0 |
| Portugal Nacional Women | 2021/12/19 14:30 | Benfica Women v Vilacondense Women | W | 3-2 |
| Portugal Nacional Women | 2021/12/12 19:00 | Benfica Women v Leixoes Women | W | 3-0 |
| Portugal Nacional Women | 2021/12/05 16:00 | SC Espinho Women v Benfica Women | W | 0-3 |
| Portugal Nacional Women | 2022/02/05 17:00 | Sporting CP Women v FC Porto Women | L | 3-2 |
| Portugal Nacional Women | 2022/01/23 16:30 | FC Porto Women v Vitoria SC Women | W | 3-0 |
| Portugal Cup Women | 2022/01/22 17:30 | FC Porto Women v CS Madeira Women | W | 3-0 |
| Portugal Nacional Women | 2022/01/09 16:00 | Porto Volei Women v FC Porto Women | W | 0-3 |
| Portugal Nacional Women | 2022/01/08 15:00 | Vilacondense Women v FC Porto Women | W | 0-3 |
| Portugal Nacional Women | 2021/12/19 15:00 | FC Porto Women v Clube Kairos Women | W | 3-0 |
| CEV Cup Women | 2021/12/14 18:00 | Schweriner SC Women v FC Porto Women | L | 3-1 |
| Portugal Nacional Women | 2021/12/11 17:00 | FC Porto Women v Sporting CP Women | L | 1-3 |